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How to Calibrate the Ozone Gas Detector?
The
ozone gas detector is indispensable for the ozone preparation workshop,
chemical industry, petroleum, paper-making, textile, pharmacy, flavors and
fragrances. The ozone gas detector is based on the ultraviolet ray absorption
principle. Use the steady ultraviolet to generate ultraviolet lines and the
light-wave filters to filter out other ultraviolet light of other wavelengths.
Only the ultraviolet light with the wavelength of 253.7nm is allowed to pass. The
ultraviolet light passes the sample photoelectric sensor and the ozone
absorption pool to reach the sampling photoelectric sensor. The electric
signals passing by the sample photoelectric sensor and the sampling
photoelectric sensor are compared. The mathematical model is calculated to
obtain the ozone concentration. After clarifying the principle, we will easily
know how to calibrate the ozone detector.
There are two methods to
calibrate the ozone gas detector:
First, use the calibration device for calibration. Use
the ozone gas detector designed based on the ultraviolet light method to choose ten
test points on the ozone detector for comparison. Control the error scope
within ±1% to be qualified.
Second, use the chemical titration for calibration. The
internationally-acknowledged chemical method, namely potassium iodide and
sodium thiosulfate titration for detection of the ozone concentration. We will
also select ten test points, and compare them with ten points tested by the
chemical titration using the ozone detector.
Control the error scope within ±1%. The potassium iodide titration
method is based on the principle of using the strong oxidant, ozone, to react
with the potassium iodide to separate the iodine out to the water. The water
will then take a tea color. The chemical reaction can be written as "O3+2KI+H2O
O2+I2+KOH." Following that, use the sodium thiosulfate standard liquid for
titration, turning the ionized iodine into the sodium iodine until the reaction
terminal point with fully faded water. (The reaction chemical reaction expression
can be written as below: I2+2Na2S2O3 2NaI+Na2S4O6.) The oxygen concentration
can be written as: C= (Ana×B×2400) / V0 unit: (mg/l) (Note: Ana----Sodium
thiosulfate standard solution volume, ml;
B---Sodium thiosulfate standard solution concentration, mol/l; V0-----Other
sampling volume of ozone oxidation, ml).